If a substance is classified under multiple CLH entries, a link to the C&L Inventory is provided to allow users to view CLH information associated with the substance and no text is automatically generated for the InfoCard. Harmonised classification and labelling is a legally binding classification and labelling for a substance, agreed at European Community level. Description Alkaline Manganese Dioxide-Zinc Battery Use Portable power source Brand ENERGIZER, EVEREADY, RAYOVAC IEC Designation Included but not limited to: LR8D425, LR03, LR6, LR14, LR20, 6LR61, LR1, 4LR25Y , 6LF22 Sizes Included but not limited to: AAAA, AAA, AA, C, D, 9V, N, Lantern Image . Hazard statement: H373: May cause damage to organs through prolonged or repeated exposure . OX. Some substance identifiers may have been claimed confidential, or may not have been provided, and therefore not be displayed. Product Name Manganese Dioxide (Certified) Cat No. COVID-19 is an emerging, rapidly evolving situation. 6(5) - SDS and Declaration, EU Ecolabels - Restrictions for Hazardous Substances/Mixtures, End-of-Life Vehicles Directive - Hazardous Substances, Active Implantable Medical Devices Directive - Hazardous Substances, In Vitro Diagnostic Medical Devices Directive - Hazardous Substances, Marine Environmental Policy Framework Directive - Hazardous Substances, Medical Devices Directive - Hazardous Substances, General Product Safety Directive - Hazardous Substances, Workplace Signs - minimum requirements & signs on containers and pipes, Safety and Health of Workers at Work Directive - Hazardous Substances, Waste Framework Directive, Annex III - Waste - Hazardous Properties, Pre-Registration process, Other, CAD - Chemical Agents Directive, Art. inside a watch) or with very low concentrations considered not to pose risks to human health or the environment. Close Find out more on how we use cookies. Manganese Dioxide Acute Tox. Hazard statement Manganese Dioxide (MnO 2) 1313-13-9 12 - 50 Acute Tox. Here you can find all of the regulations and regulatory lists in which this substance appears, according to the data available to ECHA. It is the acid anhydride of permanganic acid. It is the responsibility of the substance manufacturers and importers to consult official publications, e.g. Precautionary statement(s) )]: May react violently or explosively on contact with water. For a detailed overview on identified uses and environmental releases, please consult the registered substance factsheet. Public (risk management) activities co-ordination table. Theoretically, alkaline-manganese dioxide cells have a higher capacity than Leclanche, or zinc-carbon cells, of similar sizes. The Support section provides tools and practical guidance to companies which have responsibilities under the EU chemicals legislation. Manganese(II) oxide | MnO | CID 14940 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more. It is a hard metal and is very brittle. Dilute solutions (if less than 0.7 M) LOW HAZARD. PRODUCT NAME: Lithium Manganese Dioxide Battery CR SIZES: All sizes EMERGENCY HOTLINE: 800-424-9300 (24 hr, Chemtrec) EDITION DATE: 04/18/2016 2. Note that this list is not exhaustive. Bubbles … Other relevant information includes the following: To see the full list of notified classifications and to get more information on impurities and additives relevant to classification please consult the C&L Inventory. (y* (":��tI: ��g�pԴg���x�Q������h�C���:���2�Q���ǜ�$��Axt����4�Hx�p�vM����m������X�cs�1r�%~仜�=��|���djn��S�wbs�1X솵MSogP[|�iF{��M�Q½���v��RB��JBw�pnU��@p�| O����% �\`�X2~1�$y�D_ ��R`(f( $���K���̐ plasters, cement) and rubber products. The described Product category (i.e. For manganese metal: May damage the reproductive system. The substance identifiers displayed in the InfoCard are the best available substance name, EC number, CAS number and/or the molecular and structural formulas. May be ignited by friction, heat, sparks or flames. What is the Classification and Labelling Inventory? Early symptoms include languor, sleepiness and weakness in the legs. It does not represent a new labelling, classification or hazard statement, neither reflect other factors that affect the susceptibility of the effects described, such as duration of exposure or substance concentration (e.g. 4, STOT RE 2 H302, H332, H373 (Brain) (Inhalation) Lithium* 7439-93-2 1.1 - 3.3 Water-react. Some of the most famous early cave paintings in Europe were executed by means of manganese dioxide. 1. f Inhaling Manganese can irritate the nose, throat and lungs causing coughing, wheezing and/or shortness of breath. For readability purpose, only non-confidential use descriptors occurring in more than 5% of total occurrences are displayed. Slags coming from old converters, as in the Thomas process in the steel industry, can be used as fertilizers. PREVENT … CDC - NIOSH Pocket Guide to Chemical Hazards - Manganese compounds and fume (as Mn) Skip directly to site content Skip directly to page options Skip directly to A-Z link … manganese dioxide hazards & manganese dioxide hazards online Wholesalers - choose manganese dioxide hazards from 0 list of China manganese dioxide hazards Manufacturers. 1313-13-9 Revision Date 1987-01-01 SARA 311/312 Hazards Acute Health Hazard, Chronic Health Hazard Massachusetts Right To Know Components No components are subject to the Massachusetts Right to Know Act. External links . Manganese dioxide can slightly stain human skin if it is damp or in a heterogeneous mixture, but the stains can be washed off quite easily with some rubbing. machine wash liquids/detergents, automotive care products, paints and coating or adhesives, fragrances and air fresheners) and indoor use in long-life materials with low release rate (e.g. The ‘Substance identity’ section is calculated from substance identification information from all ECHA databases. The quality and correctness of the information submitted to ECHA remains the responsibility of the data submitter. This practice obviously puts workers at risk to the toxic effects of the dust. It is a dangerous oxidizer and was first described in 1860. electricity, steam, gas, water) and sewage treatment. Hazard statement(s) H319 Causes serious eye irritation. 2, Acute Tox. <> Do not incinerate except for disposal in a controlled incinerator. ECHA organises consultations to get feedback from all interested parties and to gather the widest possible range of scientific information for the regulatory processes. Many hazardous reactions … Additionally, if available, information on the use of the substance and how consumers and workers are likely to be exposed to it can also be displayed here. This volatile liquid is highly reactive and more often discussed than intentionally prepared. If at least one company has indicated that the substance classification is affected by impurities or additives, this will be indicated by an informative sentence. Flash point: 535 °C (995 °F; 808 K) Related compounds Other anions. First Aid Measures 4.1. 1313-13-9) Revision Date: 2007-07-01 SARA 311/312 Hazards: Acute Health Hazard, Chronic Health Hazard Massachusetts Right to Know Components No components are subject to the Massachusetts Right to Know Act. f under the OSHA Access to Employee Exposure and Medical Exposure to Manganese can cause “metal fume fever.” Substances may have impurities and additives that lead to different classifications. Solid and concentrated solutions (if 0.7 M or more) HEALTH ENVIRONMENT . W. ARNING: may cause damage to organs though prolonged or repeated exposure. MDL number MFCD00003463. Substances which have been registered and can be placed on the EEA market by those companies with a valid registration. 2, Acute Tox. If generated, an InChI string will also be generated and made available for searching. The precautionary measures and guidance on safe use are as submitted to ECHA by registrants under the REACH Regulation. Section VI: Health Hazard Data Route of Entry: MANGANESE DIOXIDE.doc Laguna Clay Company Page 1of2 Not combustible LEL NA Foam, CO2, dry chemical or water. f Inhaling Manganese can irritate the nose, throat and lungs causing coughing, wheezing and/or shortness of breath. Colloidal manganese, Manganese-55, Manganese metal A lustrous, brittle, silvery solid. Uses advised against Food, drug, pesticide or biocidal product use. Continued exposure can damage the lungs, liver, and kidneys. 1. REACH regulation aims to improve the protection of human health and the environment from the risks that can be posed by chemicals. 2(b)(i) - Hazardous Agents, Construction Product Regulation - Annex I (3) - Hazardous Substances, Construction Product Regulation - Art. May be ignited by friction, heat, sparks or flames. Manganese compounds used by potters are inorganic , like manganese dioxide, oxide and manganese carbonate. Early symptoms include sluggishness, sleepiness, and weakness in the legs. This substance is used in the following areas: formulation of mixtures and/or re-packaging and municipal supply (e.g. External links . Advanced cases have shown fixed facial expression, emotional disturbances, spastic gait, and falling. There are reports that patients have developed major symptoms several years after exposure to manganese had ceased. This list contains hazardous substances based on Table 3 of Annex VI to the CLP Regulation 1272/2008/EC. 4, Repr. InfoCards are generated automatically based on the data available at the time of generation. metal, wooden and plastic construction and building materials). Such notifications are required for hazardous substances, mixtures, or articles, manufactured or imported at over 1 kg per annum. Technetium dioxide Rhenium dioxide: Related manganese oxides. Uses advised against Not for food, drug, pesticide or biocidal product use Details of the supplier of the safety data sheet Emergency Telephone Number CHEMTRECÒ, Inside the USA: 800-424-9300 CHEMTRECÒ, Outside the USA: 001-703-527 … Manganese dioxide will release chlorine gas in contact with hydrochloric acid. The molecular structure is based on structures generated from information available in ECHA’s databases. Harmonisation is based on the substance’s physical, toxicological and eco-toxicological hazard assessment. Colloidal manganese, Manganese-55, Manganese metal A lustrous, brittle, silvery solid. 2 H319 1,2 dimethoxy ethane (DME)** 110-71-4 1 - 3.5 Flam Liq. Manganese (Mn) is a hard, gray metal that is frequently used in the production of steel. Cylindrical Lithium Manganese Dioxide Cells and Batteries (Perchlorate Style) Manufacturer Name/Address Ultralife Corporation 2000 Technology Parkway Newark, NY 14513 24 Hour Emergency Contact ChemTrec 800-424-9300 (US) 703-527-3887 (International) Technical Contact 800-332-5000 Issue Date 02 MAY 01 Prepared By Dave Gould Revision Date: 15 DEC 20 Section 2 - HAZARDS … Substances according to Hazardous Waste Properties: Annex III, Directive 2008/98/EC, 22 November 2008, amended by Directive 2018/851/EU, 14 June 2018, Registration, Evaluation, Authorisation and Restriction of Chemicals, Chemical Agents Directive and Carcinogens or Mutagens Directive, Safety and/or Health Signs at Work Directive, EC Inventory, Pre-Registration process, CAD - Chemical Agents Directive, Art. Extinguishing Media: Use dry chemical, alcohol foam, water or carbon dioxide as appropriate for the surrounding fire. In the event offire, wear full protective clothing and NIOSH-approved self-containedbreathing apparatus with full face piece operated in the pressure demand orother positive pressure mode. Manganese Dioxide Flinn Scientific, Inc. P.O. Release to the environment of this substance can occur from industrial use: in the production of articles. Manganese dioxide CAS-No. Additionally, the classification provided by companies to ECHA in REACH registrations identifies that this substance causes damage to organs through prolonged or repeated exposure. Hazard statement Manganese Dioxide (MnO 2) 1313-13-9 12 - 50 Acute Tox. The molecular formula identifies each type of element by its chemical symbol and identifies the number of atoms of each element found in one discrete molecule of the substance. A stolid mask-like appearance of the face, emotional disturbances such as uncontrollable laughter and a spastic gait with tendency to fall in walking are findings in more advanced cases. Up to 5% is required. OSHA defined hazardsNot classified. Other release to the environment of this substance is likely to occur from: indoor use in long-life materials with low release rate (e.g. 1313-13-9) Revision Date: 2007-07-01 SARA 311/312 Hazards: Acute Health Hazard, Chronic Health Hazard Massachusetts Right to Know Components No components are subject to the Massachusetts Right to Know Act. Chronic manganese poisoning can result from excessive inhalation and ingestion exposure and involves impairment of the central nervous system. Chemsrc provides Manganese dioxide(CAS#:1313-13-9) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. H335 May cause respiratory irritation. 6(5) - SDS and Declaration, EU Ecolabels - Restrictions for Hazardous Substances/Mixtures, End-of-Life Vehicles Directive - Hazardous Substances, Active Implantable Medical Devices Directive - Hazardous Substances, In Vitro Diagnostic Medical Devices Directive - Hazardous Substances, Marine Environmental Policy Framework Directive - Hazardous Substances, Medical Devices Directive - Hazardous Substances, General Product Safety Directive - Hazardous Substances, Workplace Signs - minimum requirements & signs on containers and pipes, Safety and Health of Workers at Work Directive - Hazardous Substances, Waste Framework Directive, Annex III - Waste - Hazardous Properties, C&L Inventory, Registration dossier, Other, Manganese dioxide , MnO2 , electrolytic manganese dioxide , EMD, manganese oxide,mangandioxid,mangan(IV) oxid,Braunstein..etc. Manganese can also cause Parkinson, lung embolism and bronchitis. The ‘Hazard classification and labelling’ section shows the hazards of a substance based on the standardised system of statements and pictograms established under the CLP (Classification Labelling and Packaging) Regulation. Some of the most famous early cave paintings in Europe were executed by means of manganese dioxide. It occurs naturally as Pyrolusite and which is also considered as the manganese ore. According to the harmonised classification and labelling (CLP00) approved by the European Union, this substance is harmful if swallowed and is harmful if inhaled. Warning! Hazard class: Acute toxicity, oral (Category 4). The CLP Regulation ensures that the hazards presented by chemicals are clearly communicated to workers and consumers in the European Union through classification and labelling of chemicals. If no EU harmonised classification and labelling exists and the substance was not registered under REACH, information derived from classification and labelling (C&L) notifications to ECHA under CLP Regulation is displayed under this section. (Chemical Council on Environmental Quality; Chemical Hazards to Human Reproduction, 1981). Release to the environment of this substance can occur from industrial use: formulation in materials and in the production of articles. Manganese(IV)dioxide | MnO2-4 | CID 10197621 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more. This substance is used in the following products: coating products, adhesives and sealants, fillers, putties, plasters, modelling clay, polymers, adsorbents, air care products, fuels, plant protection products, oil and gas exploration or production products and electrolytes for batteries. Manganese(II) sulfate. This substance is used in the following products: adhesives and sealants, adsorbents, coating products, fuels and oil and gas exploration or production products. metal, wooden and plastic construction and building materials). in case of consumer and professional uses). The purpose of the information provided under this section is to highlight the substance hazardousness in a readable format. Some are transported in flammable liquids. Manganese dioxide CAS Number: 1313-13-9 EC Number: 215-202-6 The hazard endpoint for which vertebrate testing was proposed: ... scientifically valid information and studies that address the relevant substance and the hazard endpoint mentioned above for which testing is proposed. flooring, furniture, toys, construction materials, curtains, foot-wear, leather products, paper and cardboard products, electronic equipment) and outdoor use in long-life materials with low release rate (e.g. 2(b)(i) - Hazardous Agents, Construction Product Regulation - Annex I (3) - Hazardous Substances, Construction Product Regulation - Art. HAZARD IDENTIFICATION We would like to inform our customers that these batteries are exempt articles and are not subject 1. If available, additional information on classification and labelling (C&L) is derived from REACH registration dossiers submitted by industry. 1313-13-9 Revision Date 1987-01-01 SARA 311/312 Hazards Acute Health Hazard, Chronic Health Hazard Massachusetts Right To Know Components No components are subject to the Massachusetts Right to Know Act. Substances Rendering Goods Ineligible for EU Ecolabel, Article 6(6), Regulation 66/2010/EC, L 27/1, 30 January 2010 (Table 3 of Annex VI to CLP; Candidate List of SVHCs), EU. Ultra high purity and high purity compositions improve both optical quality and usefulness as scientific standards. The EU Ecolabel may not be awarded to substances or mixtures classified as such. 2 R-phrases: R20/22: S-phrases (S2), S25: Related compounds Other anions: Manganese disulfide: Other cations: Technetium dioxide Rhenium dioxide: Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Manganese(IV) oxide activated, ~85%, <10 μm Synonym: Manganese dioxide CAS Number 1313-13-9. This is unique source of information on the chemicals manufactured and imported in Europe. May be harmful if swallowed (H303). Compliant with the OSHA Hazard Communication Standard 1910.1200 and aligned with the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Made in the United States of America . Manganese dioxide (CAS-No. x��R�N�0��_��]��? This information is only displayed if the substance is well–defined, its identity is not claimed confidential and there is sufficient information available in ECHA’s databases for ECHA’s algorithms to generate a molecular structure. 6 0 obj Manganese dioxide can slightly stain human skin if it is damp or in a heterogeneous mixture, but the stains can be washed off quite easily with some rubbing.
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